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　　在農(nóng)化領(lǐng)域，有一種化學(xué)結(jié)構(gòu)幾乎隨處可見(jiàn)，這就是吡啶。吡啶從結(jié)構(gòu)上看，是含有一個(gè)氮雜原子的六元雜環(huán)化合物。在應(yīng)用上，吡啶可以說(shuō)是一種“橫掃”三藥(農(nóng)藥、醫(yī)藥、獸藥)的重要中間體，不僅市場(chǎng)需求大，而且對(duì)推動(dòng)農(nóng)化等行業(yè)的綠色發(fā)展也具有極其重要的作用。 </p> <p> 　　記者了解到，吡啶類特種精細(xì)化學(xué)品種類繁多，其中又以氯代吡啶一類為發(fā)展?jié)摿艽蟮母吒郊又诞a(chǎn)品。此類產(chǎn)品在農(nóng)化、日用、醫(yī)藥等領(lǐng)域，起著不容小覷的作用。 </p> <p> 　　歷史悠久有植保處就有它 </p> <p> 　　在農(nóng)化領(lǐng)域，吡啶類農(nóng)藥被稱為第四代農(nóng)藥，具有高效、低毒的特點(diǎn)；與人和生物具有良好的環(huán)境相容性，符合農(nóng)藥的發(fā)展要求和趨勢(shì)。含吡啶環(huán)的化合物已成為農(nóng)藥創(chuàng)制的主要方向之一。 </p> <p> 　　其中，市場(chǎng)容量巨大的高效低毒農(nóng)藥毒死蜱，其生產(chǎn)制造過(guò)程中的重要中間體就是氯代吡啶類化學(xué)品？2,3,5,6-四氯吡啶。而新煙堿類殺蟲(chóng)劑第一代明星產(chǎn)品？吡蟲(chóng)啉的重要中間體，也是氯代吡啶類產(chǎn)品2-氯-5-氯甲基吡啶。 </p> <p> 　　吡蟲(chóng)啉的推廣史可謂燦爛輝煌，自上市以來(lái)，短短3年內(nèi)已遍布全球40余個(gè)國(guó)家，如今更可以說(shuō)是“有植保處，就有吡蟲(chóng)啉”。而有吡蟲(chóng)啉處，當(dāng)然也少不了氯代吡啶的身影。除了吡蟲(chóng)啉以外，殺蟲(chóng)劑烯啶蟲(chóng)胺亦是以氯代吡啶為重要中間體的新煙堿類殺蟲(chóng)劑。 </p> <p> 　　而在除草劑領(lǐng)域，氯代吡啶更是隨處可見(jiàn)。比如全球僅次于草甘膦和百草枯的第三大滅生性除草劑？敵草快。此類除草劑的重要中間體正是氯代吡啶類產(chǎn)品2-氯吡啶。 </p> <p> 　　專家認(rèn)為，隨著高毒農(nóng)藥百草枯水劑被禁用，以及市場(chǎng)第一大頭草甘膦屢陷致癌風(fēng)波，敵草快的市場(chǎng)容量將進(jìn)一步擴(kuò)大。每噸敵草快生產(chǎn)需要消耗900kg的2-氯吡啶，2-氯吡啶亦將迎來(lái)更廣闊的發(fā)展空間。 </p> <p> 　　前景光明接棒第五代農(nóng)藥 </p> <p> 　　如果僅能用于生產(chǎn)低差異性、低附加值的普通農(nóng)化產(chǎn)品，氯代吡啶的價(jià)值還不值得大書特書。即使是具有全新作用機(jī)理的新一代綠色農(nóng)藥，其關(guān)鍵中間體的制備依然離不開(kāi)氯代吡啶。 </p> <p> 　　比如在最新的第五代殺蟲(chóng)劑中，最著名的就是杜邦專利產(chǎn)品氯蟲(chóng)苯甲酰胺。記者了解到，氯蟲(chóng)苯甲酰胺屬雙酰胺類殺蟲(chóng)劑，此類殺蟲(chóng)劑自成一派，被單獨(dú)編隊(duì)為“其他殺蟲(chóng)劑”。 </p> <p> 　　由于有了氯蟲(chóng)苯甲酰胺的加盟，“其他殺蟲(chóng)劑”的市場(chǎng)表現(xiàn)甚為亮眼，銷售額一路直上。歷經(jīng)時(shí)日，如今已與曾經(jīng)的市場(chǎng)第一大戶新煙堿類殺蟲(chóng)劑不分伯仲。而究其合成過(guò)程中的關(guān)鍵中間體，依然是氯代吡啶類的化學(xué)品2,3-二氯吡啶。 </p> <p> 　　2,3-二氯吡啶屬高附加值的特種精細(xì)化學(xué)品，用量雖不多，但利潤(rùn)可觀，且近年來(lái)增長(zhǎng)速度極快。據(jù)了解，杜邦專利預(yù)計(jì)將于2022年到期，屆時(shí)氯蟲(chóng)苯甲酰胺有望成為氯代吡啶重要下游產(chǎn)品，進(jìn)一步拉動(dòng)需求增長(zhǎng)。 </p> <p> 　　應(yīng)用廣泛需求量持續(xù)攀升 </p> <p> 　　除了除草殺蟲(chóng)，氯代吡啶還可以用于生產(chǎn)氮肥穩(wěn)定劑四綠草定。 </p> <p> 　　氮肥在施用過(guò)程中，因受到脫氮、揮發(fā)、淋溶、土壤固定以及表面徑流等作用，會(huì)有高達(dá)50%以上的氮元素?fù)p失，使氮肥的作用大大降低，同時(shí)還會(huì)帶來(lái)土壤酸化、生物多樣性減少等一系列環(huán)境問(wèn)題。而氮肥穩(wěn)定劑旨在提高氮肥利用率，防止氮元素流失。這一過(guò)程中，氯代吡啶的作用必不可少。由于氮肥是化肥市場(chǎng)的“老大哥”，全球氮肥消費(fèi)量約占全部化肥消費(fèi)量的60%以上，這給了氯代吡啶很大的發(fā)展空間。 </p> <p> 　　氯代吡啶的作用遠(yuǎn)不僅限于工業(yè)，在日用和醫(yī)藥領(lǐng)域也隨處可見(jiàn)它的身影。記者了解到，氯代吡啶可以用來(lái)生產(chǎn)殺菌劑ZPT，該產(chǎn)品廣泛應(yīng)用于洗發(fā)水，包括海飛絲、飄柔等百姓耳熟能詳?shù)钠放凭羞@一成分。而在醫(yī)藥領(lǐng)域，氯代吡啶又是抗組胺類藥物非尼拉敏、中樞興奮藥利他靈、曲唑酮和抗心律失常藥丙吡胺等藥物的重要中間體。 </p> <p> 　　記者了解到，我國(guó)是氯代吡啶的主要生產(chǎn)地。未來(lái)幾年，2-氯吡啶、四氯吡啶等產(chǎn)品將進(jìn)一步規(guī)?；?、集中化，各種氯代吡啶產(chǎn)能將達(dá)4萬(wàn)~6萬(wàn)噸。而從全球范圍看，2-氯吡啶全球用量4萬(wàn)噸，四氯吡啶全球用量5萬(wàn)噸，2,3-二氯吡啶全球用量1.8萬(wàn)噸，2-氯-5-氯甲基吡啶2.8萬(wàn)噸，各種氯代吡啶的需求量約達(dá)15萬(wàn)噸，市場(chǎng)空間巨大。 </p> <p> 　　“任你產(chǎn)品更迭，我自巋然不動(dòng)”，氯代吡啶在“三藥”領(lǐng)域的戰(zhàn)績(jī)不可謂不輝煌。而根據(jù)《石化和化學(xué)工業(yè)發(fā)展規(guī)劃(2016~2020)》和《農(nóng)藥工業(yè)“十三五”發(fā)展規(guī)劃》，未來(lái)我國(guó)農(nóng)藥產(chǎn)品結(jié)構(gòu)將發(fā)生深度調(diào)整，環(huán)境友好型農(nóng)藥產(chǎn)量提高到70%以上。屆時(shí)，新型綠色環(huán)保農(nóng)藥將迎來(lái)自己的新時(shí)代，作為重要中間體，氯代吡啶也將隨之走上新征程。 </p> </div> <br /> <div style="clear:both;"></div> </div> </div> </div> <script type="text/javascript"> $(function(){ var layer = $('#layer14A9FD8EF722F8EA02772656EB8AF7F4'); layer.find('.prevlist,.nextlist').mouseenter(function(e){ $(this).find('.up_arrow,.down_arrow').addClass("arrowbj"); $(this).find('.prev_next_text,.prev_next_link').addClass("arrowfontcolor"); $(this).css("cursor","pointer"); }).mouseleave(function(e){ $(this).find('.up_arrow,.down_arrow').removeClass("arrowbj"); $(this).find('.prev_next_text,.prev_next_link').removeClass("arrowfontcolor"); }); var this_span = 0; var sharelen = 0; 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